Ayako Mitsuzuri

A stellar athlete, and captain of the archery dojo. Ayako and Rin are actively competing to see who will be the first to snag a boyfriend. She is victimized by Rider or Caster early in the story and later found unconscious in an alleyway. In the anime, Ayako is seen with Shinji after her disappearance, although Shinji denies it when asked by Shiro. Ayako often asks Shirou to come to the archery dojo and watch them practice.

(Source: Wikipedia)